"Thankful that Vanessa & my children are safe and unharmed after the incredibly scary situation that occurred this morning", Trump Jr. tweeted back in February 2018.
It's estimated Donald Jr's net worth is £107 million, according to the International Business Times.
The couple, who married in 2005, went on to ask for privacy.
Divorce is tough enough, and it'll surely be a huge change for the couple's five children - Kai Madison, 10, Donald III, 9, Tristan, 6, Spencer, 5, and Chloe Sophia, 3.
Donald Trump's sister, Maryanne Trump Barry who was then a judge in the United States court of appeals for the third circuit officiated the marriage.
The day after that smiley snap, Page Six reported that Vanessa hired a famed criminal defense attorney to represent her in the divorce.
After opening the envelope, Vanessa was hospitalized with nausea - although the powder turned out to be harmless.
When he is not traveling overseas to represent the family business, Trump Jr.is busy with his controversial hobby: hunting.
Lastly, members of Trump Jr.'s inner circle have been increasingly getting nervous with his provocative posts on his page. They were reportedly introduced to each other by President Trump.
According to Google Trends, the phrase "Melania Trump files for divorce" has surged 70 percent over the past hour in the early morning of Friday, March 16.
Meanwhile, Braxton Family Values fans also saw Tamar Braxton's explosive marriage to Vincent Herbert evaporate on the television show.
Enstars has reached out to the Trump Organization for a comment.